Thanks TreeMD, that does help. The precise nature of water in living trees still has some mystery to it, although much less mystery than in my student days. Part of the story is that water in the apoplast (the network of cell walls and open cell lumens) isn't necessarily pure water. Xylem water can contain some level of anti-freeze in the form of sugar alcohols and other not readily metabolizable carbohydrates. The water that evaporates is essentially pure and the antifreeze is left behind within the tree, which is good. We do know that water in xylem vessels and tracheids is often in a meta-stable state. If you just took a partially filled capillary tube of water and subjected it to the normally low, negative pressures and ambient temperatures, the water would flash from liquid to vapor. *However* in the living tree, those tubes and capillaries are filled continuously along the full length of root, stem, branch, and if present, leaves. That way, the water can withstand those very negative pressures (which we can call "tension) and still be liquid. Sounds like you are an inquisitive person!
Some of the clusters of ice crystals we see on conifer needles in winter is indeed rime ice which is formed from atmospheric water vapor that immediately condenses as ice crystals on cold surfaces, without forming a perceptible liquid phase. I see that infrequently, but especially in mountains of the northeast. I'm sure it occurs other places as well, but it takes a pretty special set of weather conditions to form.