Not sure why you would, unless you just so love touching the bar/chain that you can't wait until the saw is turned off...
But seriously, it's probably a bad habit, since I know that on some saws, especially the biggest ones, the chain can move a little bit even with the brake applied. Happens with my 3120 when using a shorter bar.
Although, even with the above in mind, you wouldn't touch the bar/chain with your left hand while your right was revving the engine, unless you were TRYING to hurt yourself.
So, I wouldn't mind it if my employee did it - but I might ask that they make sure the chain brake is engaged.
There are very few places where you would need to do this, unless you are being lazy. Really, how hard is it to re-start the saw after you've got done touching the bar and chain? And what can you do - check the tension? That's about it - you can't adjust it...