I agree with Joe; Experience is the best Teacher.
But some responses:
"skim the industry journals and magazines"
Maybe a little in-depth skimming would benefit.
"When there is a need to prune, I shoot for the 10% or less rule."
That guideline is only for very old or weakened trees. i took about 85% off an apple tree last month. It needed it.
"I only deadwood when it's needed for safety or requested for aesthetics."
What about health? check that thread again.
"My concerns are along the lines of; at what point does structural pruning do more harm than good?"
When too much is taken off at a time. Sprouting patterns can indicate this.
" How large a girdling root is too big to cut?"
It depends. The 4" elm sgr that was cut and pictured in the TCI article closed in 3 years. If you're in the area stop by--it's right next to the stable. 8" is probably the largest I've cut, on a yoshino cherry.
"If large limbs are removed from angiosperms, what's the best time to prune
No time is good for any kind of tree. Better to reduce, and clear enough above to give it light to live.
"(avoid suckering)?"
Sprouting around individual branch wounds can be a very good thing, as it nourishes callus growth.
Remember--In depth!